“…For instance, TiO2/Co-g-C3N4 [16], TbxOy loaded TiO2-oriented nanosheets [17], N-doped TiO2-carbon composite fibres [18], Cu-doped TiO2 nanoparticles modified with 8-hydroxyquinoline [19], carbon nitride loaded into titanium incorporated SBA-15 mesoporous silica (Ti-SBA15-CN) [10], and CdS/TiO2 [20] have been successfully applied for simultaneous removal of metal ions and organic pollutants. For a more efficient use of visible light, various narrow-band gap semiconductor photocatalysts, such as BiVO4 [21], bismuth oxyiodide/reduced graphene oxide/bismuth sulphide (BiOI/rGO/Bi2S3) [22], PANI-sensitized g-C3N4/ZnFe2O4 heterostructure [23] 2O3 -Bi2O2CO3 composite [24], and Au-Pd nanoparticles loaded on g-C3N4/MCM-41 [25] have been investigated for this photochemical process. Nevertheless, it is well-established that some of these photocatalysts have certain disadvantages such as photo-corrosion and instability.…”
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
“…For instance, TiO2/Co-g-C3N4 [16], TbxOy loaded TiO2-oriented nanosheets [17], N-doped TiO2-carbon composite fibres [18], Cu-doped TiO2 nanoparticles modified with 8-hydroxyquinoline [19], carbon nitride loaded into titanium incorporated SBA-15 mesoporous silica (Ti-SBA15-CN) [10], and CdS/TiO2 [20] have been successfully applied for simultaneous removal of metal ions and organic pollutants. For a more efficient use of visible light, various narrow-band gap semiconductor photocatalysts, such as BiVO4 [21], bismuth oxyiodide/reduced graphene oxide/bismuth sulphide (BiOI/rGO/Bi2S3) [22], PANI-sensitized g-C3N4/ZnFe2O4 heterostructure [23] 2O3 -Bi2O2CO3 composite [24], and Au-Pd nanoparticles loaded on g-C3N4/MCM-41 [25] have been investigated for this photochemical process. Nevertheless, it is well-established that some of these photocatalysts have certain disadvantages such as photo-corrosion and instability.…”
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
“…[22] As shown in Figure 3e-h, highly resolved lattice spacings of 0.19, 0.28, and 0.32 nm are observed in the high-resolution TEM image, originating from the (222), ( 002) and (201) crystal planes of Bi 2 O 3 , respectively, which certificates Bi 2 O 3 has been successfully prepared. [23] The element mapping (Figure 3i-m) analysis illustrates the coexistence of elements Bi, C and O, which further confirms that the transparent ribbons are 1D porous carbon microtubes, and particles of different sizes are Bi 2 O 3 .…”
Multi-size Bi 2 O 3 nanoparticles supported by 1-dimensional (1D) porous carbon microtubes (ms-Bi 2 O 3 /CMTs) were favorably constructed through surface-ion release and in-situ oxidation strategy. The prominent 1D porous microtube materials with multi-size nanoparticles structure can furnish more plentiful electrochemical active sites and shorten lithium storage paths for high-speed redox reactions, which was conducive to ion transport kinetics. The CV tests with various scan rates verified lithium storage mechanism of ms-Bi 2 O 3 /CMTs with diffusion/ capacitance control coexistence. The complexes illustrated an ultra-long cycle life and extraordinary reversible capacity: it still had a specific capacity of 392.6 mAh g À 1 after 3000 cycles at 1 A g À 1 ; and it manifested 546.3 mAh g À 1 when it returned to 0.05 A g À 1 and continued to 100 cycles after experiencing different current densities of 0.05-5 A g À 1 , which indicated that ms-Bi 2 O 3 /CMTs is a prospective anode for lithium-ion batteries (LIBs).
“…The band groups of CO 3 −2 at ν 1 , ν 2 , ν 3 , ν 4 and ν 1 + ν 4 reveal the formation of Bi 2 O 2 CO 3 . Moreover, the bands at 844 cm −1 and 300 -800 cm −1 are corresponded to Bi-O-C and stretching modes of the Bi-O bonds in Bi 2 O 2 CO 3, and Bi 2 O 3 , respectively 53 .…”
In this research, novel α-Bi2O3/Bi2O2CO3/(BiO)4CO3(OH)2 multi-heterojunction photocatalytic nanoflakes are fabricated via submerged DC electrical arc discharge in urea in water solution. FT-IR, XRD, EDS and PL results conform the formation of α-Bi2O3/Bi2O2CO3/(BiO)4CO3(OH)2 multi-heterojunction. Formation of nanoflake morphology are revealed by FE-SEM, TEM images. Based on UV-visible results the calculated band gap energies are in the range between 2.7 and 3.0 eV for fresh sample and after one month. The photocatalytic performance of sample is investigated via degradation of methylene orange (MeO) under visible light irradiation. α-Bi2O3/Bi2O2CO3/ (BiO)4CO3(OH)2 exhibited much higher photocatalytic activity than Bi2O2CO3, Bi2O3 and Bi2O3/Bi2O2CO3. Also, stable photodegradation efficiency of sample after four cycles reveal the long term stability and reusability of synthesized photocatalyst. PL intensity show improved separation rate of electrons and holes and so better photocatalytic performance of multi-heterojunction in compared to single phase photocatalyst. The enhanced photocatalytic activity can be ascribed to the formation of multi-heterojunctions, flake morphology and intrinsic internal electric field (IEF). Multi-heterojunction nanoflakes enhance the absorbance of visible light and facilitate the separation and transport of photogenerated electron-holes through large IEF which enhance the photocatalytic activity. Our work offers an effective method for production of innovative bismuth based photocatalyst with excellent prospective for degradation of environmental pollutions and light harvesting for renewable energy generation under visible-light.
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