Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons

Salunkhe, Rahul R.; Kamachi, Yuichiro; Torad, Nagy L.; Hwang, Soo Min; Sun, Ziqi; Dou, Shi Xue; Kim, Jung Ho; Yamauchi, Yusuke

doi:10.1039/c4ta04277h

Cited by 437 publications

(169 citation statements)

References 47 publications

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“…For example, they have been used as supercapacitor [3][4][5], catalyst support [6][7][8] and adsorbent for hydrogen storage [9] as well as CO 2 capture [2,[10][11][12]. In particular, they are widely used as adsorbents to remove organic and heavy metal contaminants from water in water treatment and purification [13][14][15][16][17][18].…”

Section: Introductionmentioning

confidence: 99%

Effect of carbonization temperature on adsorption property of ZIF-8 derived nanoporous carbon for water treatment

Abbasi

Shamsaei

Leong

et al. 2016

Microporous and Mesoporous Materials

134

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Effect of carbonization temperature on adsorption property of ZIF-8 derived nanoporous carbon for water treatment, Microporous and Mesoporous Materials (2016), doi: 10.1016/j.micromeso.2016 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. AbstractThe heat treatment effect on the adsorption capabilities of nanoporous carbon particles derived from Zeolitic Imidazolate Framework-8 (ZIF-8) was investigated at 600, 1000 and 1200 C in this study. The results showed that heat treatment at 1000 C had a significant effect on the adsorption capacity of ZIF-8 (almost 10 times) for the removal of methylene blue (MB) dye from water. Nanoporous carbons were synthesized by direct carbonization of ZIF-8. SEM and TEM images showed that the carbon resulting from ZIF-8 carbonization at various temperatures retained the original structure and morphology of ZIF-8. The carbon nanoparticles carbonized at 1000 C exhibited outstanding adsorption capacities (186.3 mg/g) compared to nanoparticles carbonized at 600 C (49.5 mg/g) and 1200 C (36.7 mg/g) as wellas ZIF-8 (19.5 mg/g) due to the change in surface charge and pore size distribution. The surface functionalities of materials were also characterized by Raman Spectroscopy, N 2 M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT2 adsorption-desorption, FTIR and TGA. The surface charge of the carbon particles changed from positive (ZIF-8) to negative as a result of conversion to carbon confirmed by zeta potential of the samples. The ZIF-8 derived carbon nanoparticles were found to be efficient adsorbents for water treatment purposes due to the satisfactory adsorption properties such as high adsorption capacity and good wettability.

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Section: Introductionmentioning

confidence: 99%

Effect of carbonization temperature on adsorption property of ZIF-8 derived nanoporous carbon for water treatment

Abbasi

Shamsaei

Leong

et al. 2016

Microporous and Mesoporous Materials

134

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“…Interestingly, unlike direct carbonizs MOF-5, all the samples show type-I isotherm in nitrogen sorption tests and have a sharp distribution at the pore width of 10.6 Å (Figure 3), which is close to the pore size of ZIF-8 (12.5 Å). [66] Other samples prepared by direct carbonization of ZIF-8 generally attain higher levels of porosity, [71][72][73][74][75] especially for the PCP (Table 6, No. 9) obtained by calcining ZIF-8 at 1000 ℃ for 8 h which has BET surface area as high as 1980 m 2 /g, meanwhile, the pore size distribution keeps concentrated at 1.8 and 3.6 nm.…”

Section: Non-metal Doped Porous Carbonmentioning

confidence: 99%

Metal‐Organic Frameworks Derived Porous Carbons: Syntheses, Porosity and Gas Sorption Properties

Pei

Chen

et al. 2016

Chin. J. Chem.

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Porous carbon materials derived from metal-organic frameworks (MOFs) have been brought into stage due to the intrinsic advantages of MOFs such as high porosity and tailorable structure diversity, which might provide infinite possibility in producing porous carbons with diverse structures and various decorations. Inherited from MOFs, the porosity in carbon materials is an important factor to evaluate the performances of porous carbons (e.g. gas sorption properties, electrochemical and catalytic behaviors). Factors that affect the porosity of porous carbon materials are mainly focused on the porosity of pristine MOFs, additives and conducting conditions. However, during past decades there were still no systematical reports on the influence factors of porosity in MOFs derived porous carbon materials and corresponding gas sorption properties. In this review, we will summarize the performances of MOF-derived carbon materials (i.e. non-doped porous carbons, heteroatoms doped porous carbons, metal/metal oxide decorated porous carbons) and give a detailed discussion about the connections between the properties and four major effects (calcination temperature, loading of additional precursor, post-synthetic treatment as well as intrinsic properties of MOFs).

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“…The influences of particle size on electrochemical performances were thoroughly investigated. The large-size NPC showed a higher capacitance value of 251 F g −1 at 5 mV s −1 scan rate than that of small-size NPC due to the fact that particle aggregation and strong interaction between the fine particles limited the ability of the electrolyte to diffuse inside the deep pore surfaces [53]. In addition, the effect of carbonization temperatures (from 700 to 1000°C) on ZIF-8 precursor was also evaluated by Yamauchi et al The results indicated that the S-900 (carbonization at 900°C) achieved the highest capacitance performance in aqueous electrolytes [178].…”

Section: Metal-organic Framework-derived Carbonmentioning

confidence: 99%

“…Carbon materials are proposed as the best candidates for energy storage owing to the attractive advantages including natural abundance, easy availability, low cost, eco-friendliness, and stability. Hitherto, different dimensional (0D, 1D, 2D, 3D) carbon materials, such as carbon onions (0D) [8,[12][13][14][15], carbon nanospheres (0D) [16][17][18][19][20], carbon fibers (1D) [21][22][23][24][25][26], carbon nanotubes (1D) [27][28][29], graphenes/ graphene oxide (2D) [30][31][32][33][34][35], carbon nanosheets (2D) [36][37][38][39], hierarchically porous carbons (3D) [40][41][42][43][44], carbide-derived carbons (3D) [45][46][47][48], templated carbons (3D) [49][50][51][52], metal-organic framework (MOF)-derived carbon (3D) [53][54][55][56][57][58][59], and carbon aerogels (3D) [60][61][62]<...>…”

Section: Introductionmentioning

confidence: 99%

Recent progress in carbon-based nanoarchitectures for advanced supercapacitors

Ran

Yang

Shao

2018

Adv Compos Hybrid Mater

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Supercapacitors, possessing high power densities, have been supposed to be one of the promising energy storage devices. Among various electrode materials of supercapacitors, carbon materials with porous nanostructure are considered as the emerging and promising candidates. This feature article reviewed the recent advances in different dimensional carbon-based nanoarchitectures for supercapacitors and particularly addressed the novel synthetic strategies to improve the electrochemical performances and corresponding theoretical foundations. The state-of-the-art progress was discussed, and diverse challenges for the electrochemical properties of carbon-based materials were propounded. Furthermore, perspectives for the design and assembly of advanced carbon-based nanoarchitectures for the supercapacitor electrode materials were highlighted.

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Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons

Cited by 437 publications

References 47 publications

Effect of carbonization temperature on adsorption property of ZIF-8 derived nanoporous carbon for water treatment

Effect of carbonization temperature on adsorption property of ZIF-8 derived nanoporous carbon for water treatment

Metal‐Organic Frameworks Derived Porous Carbons: Syntheses, Porosity and Gas Sorption Properties

Recent progress in carbon-based nanoarchitectures for advanced supercapacitors

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