Fabrication of Patterned Amine Reactivity Templates Using 4-Chloromethylphenylsiloxane Self-Assembled Monolayer Films

Brandow, Susan L.; Chen, † M.-S.; Aggarwal, Ravi; Dulcey, C. S.; Calvert, and J. M.; Dressick, Walter J.

doi:10.1021/la9902082

Cited by 128 publications

(111 citation statements)

References 60 publications

Supporting

Mentioning

108

Contrasting

Order By: Relevance

“…) light pattern on the surface of the HDF-treated substrate in an oxygen-rich environment, CÀF bonds are chemically cleaved and oxidized, resulting in the formation of ÀCOOH and ÀCHO functional end groups [119,120] ( Fig. 8a), as confirmed by X-ray photoelectron spectroscopy (XPS), contact-angle measurements, and ellipsometry.…”

Section: à2mentioning

confidence: 87%

Toward the Development of Printable Nanowire Electronics and Sensors

et al. 2009

View full text Add to dashboard Cite

In recent years, there has been tremendous progress in the research and development of printable electronics on mechanically flexible substrates based on inorganic active components, which provide high performances and stable device operations at low cost. In this regard, various approaches have been developed for the direct transfer or printing of micro‐ and nanoscale, inorganic semiconductors on substrates. In this review article, we focus on the recent advancements in the large‐scale integration of single crystalline, inorganic‐nanowire (NW) arrays for electronic and sensor applications, specifically involving the contact printing of NWs at defined locations. We discuss the advantages, limitations, and the state‐of‐the‐art of this technology, and present an integration platform for future printable, heterogeneous‐sensor circuitry based on NW parallel arrays.

show abstract

Section: à2mentioning

confidence: 87%

Toward the Development of Printable Nanowire Electronics and Sensors

et al. 2009

View full text Add to dashboard Cite

show abstract

“…Dressick and coworkers were able to transform 4-(chloromethyl)phenyl chromophores into phenylaldehyde groups, which in turn could be reduced to amines. [226] Sigimura et al showed that OTS SAMs decomposed gradually upon exposure to UV light in a vacuum to generate carboxilic acid groups that were successfully treated with functionalized and fluorinated silanes. [214,215] Surface wettability could also be controlled using photolithographic methods.…”

Section: Self-assembled Monolayers On Siomentioning

confidence: 99%

Engineering Silicon Oxide Surfaces Using Self‐Assembled Monolayers

2005

View full text Add to dashboard Cite

Although a molecular monolayer is only a few nanometers thick it can completely change the properties of a surface. Molecular monolayers can be readily prepared using the Langmuir-Blodgett methodology or by chemisorption on metal and oxide surfaces. This Review focuses on the use of chemisorbed self-assembled monolayers (SAMs) as a platform for the functionalization of silicon oxide surfaces. The controlled organization of molecules and molecular assemblies on silicon oxide will have a prominent place in "bottom-up" nanofabrication, which could revolutionize fields such as nanoelectronics and biotechnology in the near future. In recent years, self-assembled monolayers on silicon oxide have reached a high level of sophistication and have been combined with various lithographic patterning methods to develop new nanofabrication protocols and biological arrays. Nanoscale control over surface properties is of paramount importance to advance from 2D patterning to 3D fabrication.

show abstract

“…They have been applied to anchor metal catalysts, 33 polymers, 34 and biomolecules. [35][36][37][38] The chemical selectivity of an amino group is based on specific chemical bonds or electrostatic attractive forces between the terminal amino groups of the silane coupling agent and the reactive moieties of the polymer.…”

Section: Monolayer Formation and Lb Film Deposition For Fluorinated Pmentioning

confidence: 99%

Functional Organized Molecular Assemblies Based on Polymer Nano-sheets

Mitsuishi

Matsui

Miyashita

2006

Polym J

View full text Add to dashboard Cite

ABSTRACT:This review describes recent topics on functional organized molecular assemblies based on ''polymer nano-sheet''. Polymer nano-sheets consisting of amphiphilic poly(alkylacrylamide)s are described as ultrathin polymer Langmuir-Blodgett films through two-dimensional hydrogen networks between polymer backbones, which have been developed to assemble various functional molecules and nanomaterials such as metal and magnetic nanoparticles. Surface modification and nanocoating using fluorinated polymer nano-sheets in confined area are given. Multicolored patterns based on structured color and photopatterning derived from nanostructures are demonstrated. The scope of polymer nano-sheets concerning the bottom-up soft nanodevice is also reviewed. [doi:10.1295/polymj.PJ2006069] KEY WORDS Polymer / Langmuir-Blodgett / Nano-sheet / Thin Film / Acrylamide / Bottom-up approaches for constructing ordered nanoscale structures in organic molecular assemblies are of interest and various techniques for preparation of organic ultrathin films have been extensively studied. Organic thin films are attractive materials for processability, ease of functionalization, light weight, and flexibility. However processing technology on a nanoscale is immature and continuous development is required. Various organic films, for example, a spincoated film, self-assembled monolayers (SAM), 1 polymer brushes, and layer-by-layer alternative adsorption via electrostatic interactions, 2 have been investigated. We have tried to prepare various polymer ultrathin films with the Langmuir-Blodgett (LB) technique. [3][4][5][6] It has been found that N-alkylacrylamide polymer shows highly oriented and well ordered monolayer at the air/water interface. Two-dimensional network of the polymer chains via hydrogen bonding interaction of amide groups on the water surface gives a stable and condensed polymer monolayer (Figure 1). A wide variety of functional molecules were incorporated in the monolayer through copolymerization method 7 and polyion complex method etc. The advantages of the polymer nano-sheet are (1) thermal and mechanical stability, (2) uniform distribution of functional molecules, and (3) ultrathin films at the nanometer scale ranged from 1.0 nm to 2.0 nm and (4) versatile molecular building blocks. Various functional polymer nano-sheets allow fabrication of soft nanodevices based on their integrated assemblies. This review shows the definition and fascinating features of polymer nano-sheets at the first session and describes recent topics of polymer nanoarchitecture based on polymer nano-sheets; fluorination of polymer nanosheets, structured color by three-dimensional nanoassemblies, conductive polymer nano-sheets and molecular logic gates driven by photo-excitation. Hybrid nanomaterials consisting of polymer nano-sheets and metal nanoparticles are also demonstrated for efficient localized surface plasmon resonance utilization. POLYMER NANO-SHEETS BY LANGMUIR-BLODGETT TECHNIQUEThe Langmuir-Blodgett (LB) technique is a powerful means for pre...

show abstract

Fabrication of Patterned Amine Reactivity Templates Using 4-Chloromethylphenylsiloxane Self-Assembled Monolayer Films

Cited by 128 publications

References 60 publications

Toward the Development of Printable Nanowire Electronics and Sensors

Toward the Development of Printable Nanowire Electronics and Sensors

Engineering Silicon Oxide Surfaces Using Self‐Assembled Monolayers

Functional Organized Molecular Assemblies Based on Polymer Nano-sheets

Contact Info

Product

Resources

About