Anti-icing
aluminum (Al) surfaces with excellent durability and
low icing adhesion strength were fabricated by forming hierarchical
structures on Al surfaces and coating silanes with low surface energy.
The Al plates were chemically etched and subsequently immersed in
hot water to realize micro–nano hierarchical roughness on the
surface. The rough Al plates were coated with a solution containing
a mixture of 1H,1H,2H,2H-heptadecafluorodecyl (FD)-trimethoxysilane and
poly(dimethylsiloxane) (PDMS)-triethoxysilane, and the wettability
and anti-icing properties of the coated surface were compared according
to the various ratios of FD and PDMS. The anti-icing surface with
2.9 wt % of the PDMS functional group exhibited a relatively low ice
adhesion strength of 25.3 kPa despite a high relative humidity of
75% (at −20.5 °C). In addition, the ice adhesion strength
achieved after 100 icing/melting cycles was 47.2 kPa, which indicated
excellent durability of the anti-icing properties. This is attributed
to the synergistic effect of PDMS and the low surface energy of FD
groups, which exhibit chain flexibility, low glass-transition temperature,
and repulsion against water molecules.