As a first step in predicting the phase equilibria in TM-Al-Ga-N systems, where TM denotes a transition metal from the first three transition series, phase equilibria are calculated in the TM-Al-N systems, and the condensed phases in equilibrium with both AlN and N 2 gas are discussed with respect to the position of the transition metal in the periodic table, temperature, and nitrogen pressure. Possible phases for use as stable electrical contacts to AlGaN are identified using these predictions, similar previous predictions for the TM-Ga-N systems and experimental findings. fraction increases, the electronic properties of the existing contacts change due to an increasing band gap and decreasing electron affinity of AlGaN, and new metallization schemes may have to be developed to accomplish good contact formation to Al x Ga 1-x N with x > 35%. New metallization schemes may also turn out to yield contacts to Al x Ga 1-x N with x ≤ 35% with superior properties to the existing contacts.The phase equilibria in the TM-Ga-N systems, where TM denotes a transition metal from the first three transition series, have previously been estimated. 30 As a first step in understanding the TM-AlGa-N systems, this article discusses the phase equilibria in the TM-Al-N systems. There are fortunately more experimentally available phase diagrams for these systems 31-42 than for the TM-Ga-N system; 30,43-47 however, many of the diagrams are not available for the conditions of most interest for processing contacts and devices. Thus, calculated ternary phase diagrams have to be used in many cases. Such an approach has been taken for systems composed of transition metals and Al-As, 48,50 In-P, 51,52 and In-As; 48,49 however, the same simple approach that has been used to calculate the ternary phase diagrams is not possible for the TM-Al-Ga-N systems due to lack of information about quarternary phases and the predominance of solution phases in the TM-Al-Ga and AlGa-N systems.This paper presents simple ternary phase diagram calculations of the TM-Al-N systems. These calcula-