Fabrication of an Organofunctionalized Talc-like Magnesium Phyllosilicate for the Electrochemical Sensing of Lead Ions in Water Samples

Abstract

A talc-like magnesium phyllosilicate functionalized with amine groups (TalcNH2), useful as sensor material in voltammetry stripping analysis, was synthesized by a sol–gel-based processing method. The characterizations of the resulting synthetic organoclay by scanning electron microscopy (SEM), X-ray diffraction, N2 sorption isotherms (BET method), Fourier transform infrared spectroscopy (FTIR), CHN elemental analysis and UV–Vis diffuse reflectance spectroscopy (UV–Vis-DRS) demonstrated the effectiveness of the process used for grafting of amine functionality in the interlamellar clay. The results indicate the presence of organic moieties covalently bonded to the inorganic lattice of talc-like magnesium phyllosilicate silicon sheet, with interlayer distances of 1568.4 pm. In an effort to use a talc-like material as an electrode material without the addition of a dispersing agent and/or molecular glue, the TalcNH2 material was successfully dispersed in distilled water in contrast to natural talc. Then, it was used to modify a glassy carbon electrode (GCE) by drop coating. The characterization of the resulting modified electrode by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) revealed its charge selectivity ability. In addition, EIS results showed low charge transfer resistance (0.32 Ω) during the electro-oxidation of [Fe(CN)6]3−. Kinetics studies were also performed by EIS, which revealed that the standard heterogeneous electron transfer rate constant was (0.019 ± 0.001) cm.s−1, indicating a fast direct electron transfer rate of [Fe(CN)6]3− to the electrode. Using anodic adsorptive stripping differential pulse voltammetry (DPV), fast and highly sensitive determination of Pb(II) ions was achieved. The peak current of Pb2+ ions on TalcNH2/GCE was about three-fold more important than that obtained on bare GCE. The calculated detection and quantification limits were respectively 7.45 × 10−8 M (S/N = 3) and 24.84 × 10−8 M (S/N 10), for the determination of Pb2+ under optimized conditions. The method was successfully used to tap water with satisfactory results. The results highlight the efficient chelation of Pb2+ ions by the grafted NH2 groups and the potential of talc-like amino-functionalized magnesium phyllosilicate for application in electrochemical sensors.

Synthesis by Melt-Polymerization of a Novel Series of Bio-Based and Biodegradable Thiophene-Containing Copolyesters with Promising Gas Barrier and High Thermomechanical Properties

“…The FTIR spectra of the copolyesters PTBB, PTHH, and PTB x H y were analyzed, and the results are presented in Figure 1 . The spectra show the characteristic bands of the thiophene ring at 3120 cm −1 , 1570–1580 cm −1 , and 711 cm −1 , which are attributed to C=C, C–H, and C–S stretch bonds, respectively [ 48 , 49 , 50 , 51 ]. The sharp peak of the phenyl ring was observed at 1577–1585 cm −1 and 750 cm −1 , and the methylene groups attached to the THH and TBB units were seen at 2930 and 2865 cm −1 , respectively.…”

Efficient Electrochemical Lead Detection by a Histidine-Grafted Metal–Organic Framework MOF-808 Electrode Material

“…Consequently, considerable endeavors have been devoted to the advancement of materials exhibiting tailored chemical and physical characteristics, with the aim of enhancing their electrochemical performance. Many materials have been used as electrode modifiers for the detection of heavy-metal ions in water, including organoclays, ,− carbon nanotubes, and metal–organic frameworks (MOFs). − …”

Enhanced Ceftriaxone Determination using a Glassy Carbon Electrode Modified with a Cr‐Based Metal‐Organic Framework Film Stabilized by β‐Cyclodextrin Polymer

“…In these lines, thin film electrodes offer the advantage of easy incorporation and maintenance of modifiers to enhance sensor sensitivity and selectivity. [19][20][21][22] Another avenue of interest in electrode modification involves the use of metal-organic frameworks (MOFs), a class of porous materials. Yet, MOFs, with their tunable structure and surface chemistry, have promising applications in electroanalysis.…”

“…Electroanalysis, which measures the current generated during the oxidation or reduction of an analyte at electrodes, provides cost‐effective solutions in analytical chemistry. In these lines, thin film electrodes offer the advantage of easy incorporation and maintenance of modifiers to enhance sensor sensitivity and selectivity [19–22] . Another avenue of interest in electrode modification involves the use of metal‐organic frameworks (MOFs), a class of porous materials.…”