Commercial
polyolefin separators often cause explosions and thermal
runaways in lithium-ion batteries due to their poor thermal stability.
Therefore, various polymer separators with high thermal stability
have attracted the attention of researchers. In this paper, a kind
of special nano-TiO2/Polyimide (TiO2@PI) composite
separator was prepared by adding nano-TiO2 particles with
certain content to the PAA solution before electrospinning. It is
found that the added TiO2 ceramic particles greatly improve
the flame retardant performance of the separator, and at the same
time, they inhibit lithium dendrites and prevent the internal short
circuit of the battery. As a result, the TiO2@PI nanofiber
separator (5.0-TiO2@PI) prepared by a spinning solution
with a TiO2 concentration of 5.0 wt % is formed by connecting
spherical beads with a diameter of about 500 nm, which greatly inhibits
lithium dendrites. It has better properties, such as electrolyte uptake
(721%) and ionic conductivity (2.52 mS cm–1). The
LiCoO2/Li battery based on 5.0-TiO2@PI nanofiber
separator has a higher discharge capacity even at a current density
of 4 C, which is better than that of PE separator. The use of this
5.0-TiO2@PI nanofiber separator has enlightening significance
for the safety of high energy density batteries.