Multifunctional Fe 3 O 4 /Eu(DBM) 3 phen/PVP ((DBM: dibenzoylmethane, phen: 1,10-phenanthroline, PVP: polyvinyl pyrrolidone) micro bers were constructed by simple electrospinning process. The structure and morphology of the micro bers were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images. The diameters of pure PVP micro bers and the micro bers doped only with Fe 3 O 4 nanoparticles (NPs) were uniformly distributed, with an average size of about 360 nm. When 3% Eu(DBM) 3 phen complex and Fe 3 O 4 NPs were both added to the precursor for electrospinning, the micro bers became very inhomogeneous in diameter. The photoluminescent properties of pure Eu(DBM) 3 phen complex and composite micro bers were also studied. The characteristic emission peaks of Eu 3+ appeared in the composite micro bers. The intensities of emission and excitation spectra gradually decrease with adding more Fe 3 O 4 NPs. The unit mass of the pure europium complex in some composite micro bers gave stronger luminescence than the pure europium complex. The uorescence lifetime of 5 D 0 state in the composite micro bers is longer than that of pure europium complex. Additionally, the magnetic properties of Fe 3 O 4 NPs and the composite micro bers were investigated. Fe 3 O 4 NPs and composite micro bers were both superparamagnetic. The saturation magnetization of the composite micro bers was smaller than that of pure Fe 3 O 4 NPs.