Molybdenum
disulfide (MoS2) has been identified as an
active non-noble-metal-based cocatalyst for photocatalytic water splitting.
Here, a TiO2 nanoplate/amorphous MoS2 quantum
dot (a-MoS2) composite was developed via in situ sulfuration
of MoO3/TiO2. Due to intimate chemical bonding
instead of electrostatic adsorption between TiO2 and MoO3, effective transfer of electrons from TiO2 to
a-MoS2 is achieved. Additionally, a-MoS2 with
an outstanding electron conveying ability can function as an electron
collector and catalytic sites. As a result, the obtained a-MoS2/TiO2 nanocomposite achieved an average yield of
H2 up to 371 μmol·g–1·h–1 when the content of the cocatalyst was 1.5 wt %,
which is 309 and 79 times those of bare TiO2 and trigonally
coordinated MoS2/TiO2, respectively. The highest
yield rate of H2 up to 880.3 μmol·g–1·h–1 was obtained over a-MoS2/TiO2. This work may provide a wider perspective on the preparation
of a low-cost cocatalyst with high conversion efficiency, to replace
other commonly used MoS2-based cocatalysts to solve the
energy crisis.