The
heat packs that are based on solid–liquid transition
of phase-changing materials (PCMs) have been pursued as a promising
way to provide heating for human body comfort and thermotherapy owning
to their large heat storage capacity and near-constant heat-release
temperature. Current heat packs, however, suffer from leakage, slow
charging, and poor heat-release performance due to the flow of liquid
PCMs and their low thermal conductivity. Here, we report a strategy
for preparing high-performance PCM-based solar thermal heat packs
through impregnating organic PCMs within carbon-coated copper foams
(CCFs). The porous structure and hydrophobic surface of CCF help to
effectively confine the melted liquid PCM within the composite heat
pack without leakage. The carbon coating layer efficiently converts
the incident solar light into heat, which is rapidly transferred along
the three-dimensional thermal conductive network of CCF and stored
within the PCM. In the discharging process, the CCF network facilitates
the extraction of the heat stored within the PCM. In contrast to neat
PCM pack within which only a small portion of PCM that is in contact
with human skin contributes to thermal comfort, all PCMs within the
CCF-based composite heat pack concertedly release the stored heat.
Such release significantly increases the extractable thermal energy
and prolongs the usable healing duration for thermotherapy.