2010
DOI: 10.1007/s11434-010-4147-7
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Fabrication and field emission performance of arrays of vacuum microdiodes containing CuO nanowire emitters grown directly on glass without a catalyst

Abstract: Arrays of vacuum microelectronic sources are fabricated on a glass substrate using cupric oxide (CuO) nanowire emitters. The arrays of electron sources possess a microdiode structure, which can effectively induce field emission and control the delivery of emitted electrons to the anode in a triode-type device operation. A technique for precisely growing CuO nanowires at the centre of microcavities in an array without using a catalyst and at temperatures as low as 400°C is presented. Such a simplified fabricati… Show more

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Cited by 10 publications
(4 citation statements)
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“…Cupric oxide (CuO) are promising materials for gas sensors, heterogeneous catalysts, photovoltaics, infrared detectors, eld emission emitters and lithium ion electrodes applications due to their unique properties such as direct band gap (1.2-1.7 eV), nontoxicity, chemical stability, abundant availability and low production cost. [31][32][33][34][35][36][37][38] To date, most of the ways used to generate CuO nanowires (CuO NWs) are physical and chemical routes, for instance, precursor methods, hydrothermal reaction, anodization, electrospinning, and seed-mediated growth solution. [39][40][41][42][43] Compared with these methods, the formation of CuO NWs by direct thermal oxidation of Cu has been recently given considerable attention due to its simplicity and large-scale growth.…”
Section: Introductionmentioning
confidence: 99%
“…Cupric oxide (CuO) are promising materials for gas sensors, heterogeneous catalysts, photovoltaics, infrared detectors, eld emission emitters and lithium ion electrodes applications due to their unique properties such as direct band gap (1.2-1.7 eV), nontoxicity, chemical stability, abundant availability and low production cost. [31][32][33][34][35][36][37][38] To date, most of the ways used to generate CuO nanowires (CuO NWs) are physical and chemical routes, for instance, precursor methods, hydrothermal reaction, anodization, electrospinning, and seed-mediated growth solution. [39][40][41][42][43] Compared with these methods, the formation of CuO NWs by direct thermal oxidation of Cu has been recently given considerable attention due to its simplicity and large-scale growth.…”
Section: Introductionmentioning
confidence: 99%
“…Such a phenomenon was generated from a tunnelling barrier at the copper nanowire-gold junction whose effect gradually collapses as a function of increasing biasing voltage [16]. So conduction electrons possess enough mobility to overcome the energy barrier and the influence of the barrier on the transport was decreased.…”
Section: Resultsmentioning
confidence: 99%
“…Vacuum microelectronic devices, such as X-ray sources [ 1 , 2 , 3 ], photodetectors [ 4 , 5 ] and parallel electron beam lithography [ 6 ], impose high requirements on large-area field emitter arrays (FEAs). One-dimensional (1D) materials are considered ideal candidates for large-area FEAs due to their high aspect ratio and unique properties [ 7 , 8 , 9 , 10 , 11 ]. In particular, ZnO nanowires have the advantages of large-area uniform preparation, low cost and good compatibility with microfabrication techniques, and thus extensive studies have been carried out on the field emission properties of ZnO nanowires [ 12 , 13 , 14 , 15 , 16 , 17 ].…”
Section: Introductionmentioning
confidence: 99%