Fabrication and evaluation of molecularly imprinted multi-hollow microspheres adsorbents with tunable inner pore structures derived from templating Pickering double emulsions

Monolithic supermacroporous hydrogel prepared from high internal phase emulsions (HIPEs) for fast removal of Cu 2+ and Pb 2+

“…Under the same conditions, the adsorbents with high specific surface area show fast adsorption kinetics and high adsorption capacity, because the functional groups attached onto the adsorbents can be fully exposed that is beneficial for easy access of an adsorbate [9]. Therefore, the adsorbents are usually prepared as nanoparticles or porous structures displaying outstanding adsorption performances due to high surface area and abundant active sites, [10][11][12].…”

Porous and Magnetic Molecularly Imprinted Polymers via Pickering High Internal Phase Emulsions Polymerization for Selective Adsorption of λ-Cyhalothrin

“…From the Table 2, it was concluded that the Langmuir model fitted better to the adsorption isotherm data, suggesting that LC adsorption on the surface of the MMIPs and MNIPs was a surface with homogeneous binding sites and monolayer coverage (Pan et al, 2015). It can also be seen that the values of R L for MMIPs and MNIPs were 0.4933–0.5058 and 0.6944–0.7236 and 1/n were 0.7766–0.8057 and 0.8265–0.8522 respectively, indicating that the MMIPs were favorable for LC adsorption than that of MNIPs.…”

Pickering emulsion-based molecular imprinting

“…在生物样本中, 基于Pickering乳液的分子印迹技术也展现出巨大潜 力. 例如, Yang等人 [20] [21] , 我们将近年来已发表的采用Pickering乳液聚 [22,23] 、荧光 [19] 、空心 分子印迹 [22,29] 等)方向发展; (2) 向制备能在复杂样品 体系(如河水 [37,38] 、血液 [39,45] 、尿液 [20,39] [53,54] ; 对于疏水性蛋白质分子, 目前还没有利用Pickering乳液聚合成功合成蛋白质印 迹的报道. 但疏水蛋白具有在亲水-疏水界面通过自 组装形成蛋白膜的重要特性, 自组装的蛋白质颗粒本 身能作为固体颗粒稳定剂制备界面印迹MIP材料 [55] .…”