[(F6acac)Pd(μ-HNC6F5)]2, a Large Family of Polymorphs and Solvates with Short F···F Contacts
Aniffa Kouton,
Robert Pepin,
Nicholas Alexander Maciulis
et al.
Abstract:Highly fluorinated [(F 6 acac)Pd(μ-HNC 6 F 5 )] 2 was prepared by the reaction of palladium bis(hexafluoroacetylacetonate), Pd(F 6 acac) 2 , with pentafluoroaniline. This compound generates a large family of crystalline polymorphs and solvates. In this paper, we present a study on the synthesis, solution phase dynamics, and crystal structures of highly fluorinated [(F 6 acac)Pd-(μ-HNC 6 F 5 )] 2 . Pd 3 (μ-F 6 acac) 2 (μ-HNC 6 F 5 ) 4 is produced as a minor byproduct. We also describe the synthesis and structur… Show more
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