Extremely Facile Oxidative Addition of Silyl, Germyl, and Stannyl Tellurides and Other Chalcogenides to Platinum(0) Complexes. X-ray Structure of trans-Pt(4-PhC₆H₄Te)(SiMe₃)(PEt₃)₂

Element−Element Addition to Alkynes Catalyzed by the Group 10 Metals

“…80 It was shown that the formation rates of the products decreased in the order PhSeSnMe 3 > PhSeSiMe 3 ; PhTeSnMe 3 > PhTeSiMe 3 . No reaction was observed with MeSSiMe 3 .…”

“…58 In the presence of CO, the reactions of disulfides and diselenides with alkynes were shown to give products (42) of carbonylative addition 56,59 (which resembles the carbonylative hydrosilylation, Scheme 57). The insertion of CO resulted in CO-Pd bond formation.…”

Palladium selenolates via oxidative addition of organylselenenyl halides to palladium(0) precursor and via cleavage reaction of diselenides: Synthesis, structure and spectroscopic investigation

“…bis[2-(4,4-dimethyl-2-oxazolinyl) phenyl] diselenide (3)[34] and bis[2-(N,N-dimethylaminomethyl) phenyl] diselenide(18) [39] and the ditelluride viz. bis[2-(4,4- dimethyl-2-oxazolinyl)phenyl] ditelluride(16) [43] on reaction with Pd(COD)Cl 2 in dichloromethane provided the dinuclear palladium chalcogenolate bridged complexes 15, 19 and 17 respectively.…”

Trifluoromethylselenato(0) and trifluoromethyltellurato(0) complexes of platinum(II)

“…[9,10,18,20,[22][23][24][25][26] within limits of accuracy. While there are numerous platinum compounds with the structural element PtSeR (R = organic substituent) and phosphine ligands (see above) known, the number of tellurato-platinum compounds is limited [20,[27][28][29][30]. In this series, cis-[Pt(TeCF 3 ) 2 (PPh 3 ) 2 ] represents the first example of its kind.…”