“…The preconcentration factor found for this work is superior to some coprecipitation methods and other preconcentration techniques [29][30][31][32][33][34][35]. The detection limits of analytes are superior to those of preconcentration techniques [29][30][31][32][33][35][36][37][38][39][40]. The method is relatively rapid as compared with previously reported procedures for the enrichment of analyte ions ( Table 5).…”
“…The preconcentration factor found for this work is superior to some coprecipitation methods and other preconcentration techniques [29][30][31][32][33][34][35]. The detection limits of analytes are superior to those of preconcentration techniques [29][30][31][32][33][35][36][37][38][39][40]. The method is relatively rapid as compared with previously reported procedures for the enrichment of analyte ions ( Table 5).…”
“…On comparing the spectra, it was clear that in case of chelated Amberlite IR-120, new IR bands have appeared. These bands are at (N=O), 1348 cm -1 for (N-H) and δ(N-H), 1626 and 1383 cm -1 (C=O) and 1540 for N=N group [17]. Thus FTIR analysis indicated the successful chelation of Amberlite FTIR spectrum of modified Amberlite IR-120.…”
Section: Characterization Of Simple and Chelated Ir-αnβn And Ir-8hqmentioning
confidence: 87%
“…Different chelated polymer resins have been used for preconcentration of trace metals. Among these the most widely used are chelated Amberlite XAD-2 [8], XAD-7 [9], XAD-16 [10], XAD-2000 [11] and in addition activated alumina [12], and activated carbon [13] have also been used. Many chelating ligands such as quinolone, 2-amino-2-thiazoline, pyridine and aminophosphonate have been broadly used for chelating polymer resins [14].…”
ABSTRACT. In the present study, the efficiency of simple and chelating Amberlite IR-120 with α-nitroso β-naphthol (IR-αNβN) and with 8-hydroxy quinoline (IR-8HQ) has been compared for the removal of Cu(II) from aqueous solutions. The chelation was confirmed using different characterization techniques like SEM, TGA and FTIR. A number of experiments were carried out in batch system to determine the effect of different parameters on adsorption of Cu(II) like pH, contact time and sample volume. The results showed occurrence of maximum adsorption at pH 7 in 10 min with adsorption capacity of 71.5 mg g -1 at 298 K. The adsorption followed pseudo second order kinetic model among the four kinetic models applied. Maximum desorption from IR-8HQ was obtained with a mixture of 4.0 M HCl and 0.5 M HNO3. Furthermore, IR-8HQ was found to be most selective adsorbent among three adsorbents investigated. The developed preconcentration procedure was successfully applied to spiked tap water and real samples.
“…The relative standard deviation [15,[39][40][41][42] and preconcentration factor [43][44][45][46][47][48][49] of analyte ions are superior to those of preconcentration technique for analyses. The proposed method shows very good sensitivity and precision and has some good advantages over other on-line preconcentration methods reported in the literature.…”
Section: Comparison With Other Solid-phase Extraction Methodsmentioning
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