Extraction of cerium (IV) using di-n-butylsulfoxide in chloroform from nitric acid and determination with arsenazo (III) as chromogenic Reagent

Khan, Muhammad Haleem; Liaqat, Khurram; Hafeez, Muhammad; Fazil, Srosh; Riaz, Muhammad

doi:10.17159/0379-4350/2015/v68a11

Cited by 3 publications

(1 citation statement)

References 35 publications

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“…However, UV-Vis spectrophotometric methods were widely used owing to their sensitivity, rapidity, low cost, simplicity, good selectivity and wide applications. So, various analytical reagents such as; propionylpromazine phosphate [12], 4-methyl-7-hydroxycoumarin [13], 1, 3-o-hydroxyphenyl-5-phenylformazan [14], naphthol green B [15], hydrazinecarboxymide2-[(2-hydroxyphenyl) methylene [16], sulphanilic acid [17], arsenazo-III [18], 2,4-Dimethyl pentan-3-one [19] were used for the spectrophotometric determination of cerium.…”

Section: Introductionmentioning

confidence: 99%

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

et al. 2019

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N EW spectrophotometric method was proposed for the rapid and accurate determination of Ce(III) using a new synthesized sulfacetamide azo-dye reagent [N-(4-((2,3-dihydroy-5-(3,5,7-trihydroxy-4-oxo-4H-chromen-2-yl)phenyl)diazenyl) phenylsulfonyl)acetamide] [DTPPA]. The reagent was characterized by IR, 1 HNMR and mass spectra. The developed method was based on the reaction of Ce(III) with DTPPA reagent to form brown colored complex in an alkaline medium using borate buffer at pH = 9 with absorption maximum at 560 nm. The method was enhanced by the use of cationic surfactant of cetylpyridinium bromide (CPB). Different factors affecting the formation and stability of the complex such as reagent concentration, time, temperature, solvents and order of addition were also studied. The composition of the complex was found 1:2 (metal: ligand) by both Job's and molar ratio methods. The stability constant of the complex was calculated to be 3.387×10 6. Beer's law was obeyed in the concentration range of 5.0-100 µg mL-1 of Ce(III) with molar absorpitivity and Sandell's sensitivity 1.020×10 4 L mol-1 cm-1 and 0.01373 µg cm-2 , respectively. The proposed method was applied for the determination of micro-amounts of Ce(III) in some industrial and plant samples. The Ce(III) complex was also prepared in the solid state.

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Section: Introductionmentioning

confidence: 99%

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

et al. 2019

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Extraction of Cerium (III) by a Solvent Extraction Technique Using Diaminododecylphosphonic Acid (DADTMTPA): Experimental, Density Functional Theory and Molecular Dynamic Studies

et al. 2023

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This paper aims to present the recent results progress on diaminododecylphosphonic acid (DADTMTPA) as an extractant of cerium (III) from Ce(NO 3 ) 3 .6H 2 O solution medium. Different parameters including pH, temperature, extractant concentration, and foreign ions present in the aqueous phase were examined to investigate the extractional mechanism. The optimum conditions of solvent extraction of Ce(III) are as follows: under experimental conditions of 298 K and the initial concentration of Ce(III) being kept at 10 À 4 M at pH 3.50. The agitation duration of 5 min for a volume ratio equal to 2, and the best yield is 77 % in one-step. An increase in the temper-ature reduced the extraction process. The DADTMTPA extracts Ce(III) after the second cycle with a yield of 95 %. The extraction thermodynamic parameters such as ΔG, ΔH and ΔS are also determined and reported. On the other hand, density functional theory (DFT) based on B97D3 functional with 6-311 + + G(d,p) basis set analysis and molecular dynamics simulations were used to extremely fast methods at calculating the nonbonded interactions and to understand its properties of molecular interactions, which have proved to be an adopted and useful tool to predict and describe the chemical behavior of the evolution of the system.

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Liquid-liquid extraction of Nd⁺³ and Eu⁺³ from aqueous medium using oxytetracycline in dichloromethane

et al. 2021

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Liquid-liquid extraction system consisting of oxytetracycline (HOTC) in dichloromethane was developed for extraction of Nd+3 and Eu+3 from acidic solutions using radiometric technique. Various extraction parameters such as pH, equilibration time and metals concentration were optimized. Slope analysis method was used to study the composition of product and was found to be M(OTC)3 [here M=Nd+3 or Eu+3 and OTC = conjugate base of HOTC]. Among cations Al+3 and Fe+3 while among anions F− effected the extraction of these metals. Higher separation factor of these metals was found with many others. The method was successfully applied on spiked sea water.

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Extraction of cerium (IV) using di-n-butylsulfoxide in chloroform from nitric acid and determination with arsenazo (III) as chromogenic Reagent

Cited by 3 publications

References 35 publications

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

Extraction of Cerium (III) by a Solvent Extraction Technique Using Diaminododecylphosphonic Acid (DADTMTPA): Experimental, Density Functional Theory and Molecular Dynamic Studies

Liquid-liquid extraction of Nd⁺³ and Eu⁺³ from aqueous medium using oxytetracycline in dichloromethane

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Extraction of cerium (IV) using di-n-butylsulfoxide in chloroform from nitric acid and determination with arsenazo (III) as chromogenic Reagent

Cited by 3 publications

References 35 publications

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

Spectrophotometric Determination of Cerium(III) in Some Industrial and Plant Samples using New Synthesized Azo-dye Reagent: Synthesis and Characterization

Extraction of Cerium (III) by a Solvent Extraction Technique Using Diaminododecylphosphonic Acid (DADTMTPA): Experimental, Density Functional Theory and Molecular Dynamic Studies

Liquid-liquid extraction of Nd+3 and Eu+3 from aqueous medium using oxytetracycline in dichloromethane

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Liquid-liquid extraction of Nd⁺³ and Eu⁺³ from aqueous medium using oxytetracycline in dichloromethane