Extension of Heterogeneous Thermodynamic Laws on the System with the Arbitrary Components and Phases Numbers with the Help of Heterogeneous Complex Concept

The article gives a general classification of non-invariant points in phase equilibrium diagrams of all possible types. The complete topological isomorphism of the diagrams of fusibility, solubility, and liquid-vapor equilibria in various sets of variables is demonstrated. The stability of mono-variant equilibria near the non-variant points is investigated. Recurrent formulas for calculating the number of topological elements of phase diagrams are given. A previously undescribed type of non-invariant points and phase processes in the solubility diagrams is described and characterized. The last ones have no topological analogs in other types of diagrams. Thus, we have carried out, as far as is available to the authors, a complete classification of invariant points and invariant processes in phase equilibrium diagrams of an arbitrary type and with an arbitrary number of components.

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Extension of Heterogeneous Thermodynamic Laws on the System with the Arbitrary Components and Phases Numbers with the Help of Heterogeneous Complex Concept

Cited by 2 publications

References 4 publications

Algorithm (Procedure Variants) for the Calculation of Solubility Diagrams of Quasi-Simple Multicomponent Water–Electrolyte Systems

Algorithm (Procedure Variants) for the Calculation of Solubility Diagrams of Quasi-Simple Multicomponent Water–Electrolyte Systems

Non-variant phenomena in heterogeneous systems. New type of solubility diagrams points

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