Extending 2D covalent organic frameworks by inserting anthracene for promoted white-light-mediated photocatalysis

Abstract

Through the responsible manipulation of linkage chemistry on a molecular scale, the band gaps and electronic structures of two-dimensional covalent organic frameworks (2D-COFs) can be finely tuned. Intrinsically, the incorporation...

High-performance anthracene-linked covalent triazine frameworks with dual functions for CO2 capture and supercapacitor applications

“…60 The rigid, π-conjugated surface of the anthracene (ANT) molecule contributes to its high charge transfer efficiency and significant fluorescence emission. 61 Mohamed et al discovered that An-CTF-10-500 exhibits a capacitance of 589 F g −1 and a high CO 2 adsorption capacity. 62 Hence, we developed a new type of material called nitrogen-enriched CTF using the ANT moiety and molten ZnCl 2 at a high temperature of 500 °C with two different molar ratios (1 : 10 and 1 : 20), as presented in Fig.…”