Exploring the Luminescence, Redox, and Magnetic Properties in a Multivariate Metal–Organic Radical Framework
Gonçalo Valente,
Pedro Ferreira,
Miguel A. Hernández-Rodríguez
et al.
Abstract:Persistent neutral organic radicals are excellent building blocks for the design of functional molecular materials due to their unique electronic, magnetic, and optical properties. Among them, triphenylmethyl radical derivatives have attracted a lot of interest as luminescent doublet emitters. Although neutral organic radicals have been underexplored as linkers for building metal− organic frameworks (MOFs), they hold great potential as organic elements that could introduce additional electronic properties with… Show more
In this contribution we demonstrate that metal–organic frameworks (MOFs) with suitable underlying topological structure are amenable for the preparation of MOF-based substitutional solid-solutions (SSS) that follow Vegard's law.
In this contribution we demonstrate that metal–organic frameworks (MOFs) with suitable underlying topological structure are amenable for the preparation of MOF-based substitutional solid-solutions (SSS) that follow Vegard's law.
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