Exploring the impact of temperature and oxygen partial pressure on the spent nuclear fuel oxidation during its dry management

Abstract

The management of Spent Nuclear Fuel (SNF) comprises different stages in which security is demonstrated. Nevertheless, fundamental research can lead to other design options that must be considered. Currently, one of the focuses is the dry interim storage option, as the shortest-term solution until final repositories are available. During this stage, one concern is the oxidation of the fuel. If UO2 (SNF matrix) is exposed to air at high-enough temperature, formation of U3O8 takes place. The larger volume of this phase could entail stresses on the SNF clad, which is the first barrier to prevent radioactive material release. It is known that this oxidation is a temperature-dependent reaction and ensuring an inert atmosphere discards any effect during SNF dry management. However, at what extent temperature and oxygen concentration would have an impact on the U3O8 formation is not established, being the available experimental data very scarce. We follow this oxidation in representative ranges of temperature and oxygen concentration of dry storage facilities by using in-situ Raman spectroscopy. The results show that temperature is a more-affecting factor than the oxygen concentration at the studied conditions. Therefore, efforts to limit temperatures would yield more benefits in preserving fuel matrix integrity.

Characterization of Spent Nuclear Fuel Canister Surface Roughness Using Surface Replicating Molds

“…An SNF storage canister represents an ideal test specimen for this study because it is far too large for movement or direct pro lometry measurements, but it has been shown that surface roughness plays an important role in particulate deposition [16][17][18] and pitting susceptibility [19][20][21] . Therefore, understanding the variation in surface roughness across various features can provide important information for canister ageing management programs and ensure fuel integrity 22 .…”