Exploring the boundaries of ferrocenesulfonyl fluoride chemistry

Erb, William; Hurvois, Jean‐Pierre; Halauko, Yury S.; Матулис, Вадим Э.; Roisnel, Thierry

doi:10.1039/d2qi01854c

Inorg. Chem. Front.

2022

DOI: 10.1039/d2qi01854c

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Exploring the boundaries of ferrocenesulfonyl fluoride chemistry

William Erb

Jean‐Pierre Hurvois

Yury S. Halauko

et al.

Abstract: Ferrocenesulfonyl fluorides represent a new subfamily of metallocenes barely explored. Here, we describe how the use of deprotolithiation-electrophilic trapping sequences and ‘halogen dance’ reactions can afford up to 1,2,3,4,5-hetero pentasubstituted...

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2024

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Cited by 2 publications

References 193 publications

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Catalytic Approaches to the Halogen Dance Reaction for Molecular Editing

Inoue,

Okano

2024

ChemCatChem

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Transposition reactions, i.e., switching the position of functional groups, are a powerful tool for molecular editing. The transposition of a halogen atom attached to an aromatic ring, referred to as the halogen dance reaction, has great potential in the fields of pharmaceuticals, agrochemicals, natural products, and functional materials. However, the substrate scope of this reaction is limited owing to the intrinsic difficulty in facilitating multiple catalytic cycles involving several aryllithium species. In this concept paper, recent advances in halogen dance catalysis that have expanded the substrate scope of this reaction are highlighted.

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Catalytic Approaches to the Halogen Dance Reaction for Molecular Editing

Inoue,

Okano

2024

ChemCatChem

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Recent advances in the remote catalytic functionalisation of ferrocenes

Erb

2024

Dalton Trans.

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Exploring the boundaries of ferrocenesulfonyl fluoride chemistry

Abstract: Ferrocenesulfonyl fluorides represent a new subfamily of metallocenes barely explored. Here, we describe how the use of deprotolithiation-electrophilic trapping sequences and ‘halogen dance’ reactions can afford up to 1,2,3,4,5-hetero pentasubstituted...

Cited by 2 publications

References 193 publications

Catalytic Approaches to the Halogen Dance Reaction for Molecular Editing

Catalytic Approaches to the Halogen Dance Reaction for Molecular Editing

Recent advances in the remote catalytic functionalisation of ferrocenes

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