Exploring Favorable Supramolecular Interactions of Multifluorinated Aromatics in Dendronized Push‐Pull Chromophores for Electro‐Optics
Jie Zou,
Di Zhang,
Quoc Huy Thi
et al.
Abstract:Multifluorinated aromatics serve as supramolecular synthons in the research of organic electro‐optic (EO) materials by exploiting π−π stacking interaction between the aromatic hydrocarbon and multifluorinated aromatic groups for performance improvement. However, non‐classical hydrogen bonding remains largely unexplored in fluorinated EO dendrimers. In this study, three Fréchet‐type generation 1 benzyl ether co‐dendrons were synthesized by replacing one benzyl group with 2,3,5,6‐tetrafluorobenzyl (p‐HF4Bz), pen… Show more
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