Exploring Catalytic Intermediates in Pd-Catalyzed Aerobic Oxidative Amination of 1,3-Dienes: Multiple Metal Interactions of the Palladium Nanoclusters
Kazuki Tabaru,
Tetsuaki Fujihara,
Kazuyuki Torii
et al.
Abstract:Metal nanoclusters (NCs) have unique
properties because of their
small size, which makes them useful as catalysts in reactions like
cross-coupling. Pd-catalyzed oxidative amination, which involves dehydrogenative
C–N bond formation, uses Pd complexes as the active species.
It is known that the catalytic conditions involve the formation of
Pd(0) species from Pd NCs, but the precise role of Pd NCs in the transformations
has not been established. In this study, we investigated the characteristic
properties of Pd … Show more
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