We have extended the theoretical considerations of Scudder and Olbert (1979) (hereafter paper I) to show from the microscopic characteristics of the Coulomb cross section that there are three natural subpopulations for plasma electrons: the subthermals with local kinetic energy E < kTc; the transthermals with kT < E < 7 kT and the extrathermals E > 7 kT c . We present experimental support from three experimental groups on three different spacecraft in the interplanetary medium over a radial range for the five interrelations projected in paper I between solar wind electron properties and changes in the interplanetary medium: 1) subthermals respond primarily to local changes (compressions and rarefactions) in stream dynamics; 2) the extrathermal fraction of the ambient electron density should be anti-correlated with the asymptotic bulk speed; 3) the extrathermal "temperature" should be anti-correlated with the local wind speed at 1 AU; 4) the heat flux carried by electrons should be anti-correlated with the local bulk speed; and 5) the extrathermal differ ential "temperature" should be nearly independent of radius within 1 AU.From first principles and the spatial inhomogeneity of the plasma we show that the velocity dependence of Coulomb collisions in the solar wind plasma produces a bifurcation in the solar wind electron distribution function at a transition energy, E*. This energy is theoretically shown to scale with the local thermal (tp core) temperature as E*(r) A 7 kT c(r).This scaling is observationally supported over the radial range from 0.45 to 0.9 AU by Mariner 10 data and IMP data acquired at 1 AU. The extra thermals, defined on the basis of Coulomb collisions, is synonymous with 3 the subpopulation previously labeled in the literature as the "halo" or shot" component. If the transition energy should be required to equal the polarization potential energy, e(r), for all radii beyond the observer, (as motivated by Mariner 10 data) the thermal electrons should obey a polytrope law with index Y = 7/6. In this circumstance the polarization potential is equal to the specific enthalpy: e4(r) = [y/(y-1)] kTc(r).This relation probably does not obtain in the corona, inside r < 10-20 RQ (of. Paper I). In the asymptotic spherically symmetric solar wind the inverse power law index for radial variation required for the thermal electrons should be a = 1/3 which is consistent with the recent in situ determinations between 0.45 and 03 AU. We thus provide the first self-consistent argument for associating E*(r) with e0(r). This theoretical asymptotic (r -) thermal electron temperature variation is between the conduction dominated (2Z7) and the inviscid solution (2/5). In the proximity of the ecliptic the ratio of the thermal electron Coulomb mean free path to scale length is shown to decrease with increasing radial distance. By contrast, over the solar poles the same asymptotic tempera ture and density variations iiply that the, Coulomb thermal mean free path will increase with increasing radial distance.A strai...