Exploration of iron ligand modes in dimeric iron (II) complexes by nuclear resonance scattering

Omlor, Andreas; Lauk, Sergej; Müller, Christina S.; Scherthan, Lena; Auerbach, Hendrik; Hochdörffer, Tim; Wolny, Juliusz A.; Steinbrügge, René; Leupold, O.; Сергеев, И. И.; Wille, Hans Christian; Sitzmann, Helmut; Schünemann, Volker

doi:10.1007/s10751-019-1663-y

Cited by 2 publications

(1 citation statement)

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“…For example, careful hydrolysis with stoichiometric amounts of water yields the hydroxy‐bridged dimeric complex 20 h , in quantitative yields. Using nuclear inelastic scattering (NIS), both 20 a and 20 h , were investigated and Lamb‐Mössbauer factors as well as other thermodynamic parameters could be determined [43] . Treatment of 20 f with 2,5‐dimethylpyrrole gives the azaferrocene 20 i in almost quantitative yields and reacting 20 f with an excess of diphenylphosphane results in single P−H bond activation and the formation of bis(phosphine)‐hydrido‐iron complex 20 j , as well as the dehydrocoupling product 5 CpFe(H)(P 2 Ph 4 ) [44] .…”

Section: Transition Metal Compoundsmentioning

confidence: 99%

Pentaisopropyl Cyclopentadienyl: An Overview across the Periodic Table

Lauk

Schäfer

2021

Eur J Inorg Chem

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Cyclopentadienide (Cp) groups are among the most popular ligands in organometallic chemistry. Sterically demanding substitution patterns on the Cp ring can have an important effect on the ligand properties and there are many examples of metal complex which are only stable and isolatable with sterically demanding Cp ligands, carrying alkyl or aryl groups. Among these sterically demanding Cp ligands, pentaisopropylcyclopentadienide is the bulkiest pentaalkyl derivative and has been utilized in main group, as well as transition metal and rare‐earth element chemistry for several decades.

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Section: Transition Metal Compoundsmentioning

confidence: 99%