Exploiting aromaticity in fatty terephthalate diesters to enhance melting point and prevent polymorphism

Soodoo, Navindra; Poopalam, Kosheela D.; Bouzidi, Laziz; Narine, Suresh S.

doi:10.1016/j.solmat.2022.111650

Cited by 4 publications

(2 citation statements)

References 54 publications

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“…Other organic substances like pure alkanes, alcohols, and polyethylene glycol (PEG) also serve as PCMs for LHS applications and their thermophysical properties are summarized elsewhere. 117,118 Besides, the use of ester PCMs has been actively reported, [119][120][121] suggesting the broad availability of organic PCMs for TES applications.…”

Section: Phase Change Materialsmentioning

confidence: 99%

Nanocellulose-based composite phase change materials for thermal energy storage: status and challenges

Shen

Qin

Xiong

et al. 2023

Energy Environ. Sci.

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Section: Phase Change Materialsmentioning

confidence: 99%

Nanocellulose-based composite phase change materials for thermal energy storage: status and challenges

Shen

Qin

Xiong

et al. 2023

Energy Environ. Sci.

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“…The oil from jojoba seeds is a molecularly unique vegetable oil that is comprised predominantly of long-chain unsaturated monoesters with total chain lengths between 40 and 42 carbons [54,55]. Compared to TAG oils, jojoba oil, and natural wax esters have better lubricant properties and possess an exceptionally higher thermal stability and viscosity index [56,57] but are not used in large-scale commercialization because of cost and availability [58].…”

Section: Vegetable Oil As An Alternative Feedstock For Biobased Lubri...mentioning

confidence: 99%

Fundamental Structure–Function Relationships in Vegetable Oil-Based Lubricants: A Critical Review

2023

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Vegetable oil (VO)-based lubricants are environmentally friendly replacements for mineral oils. This work critically reviews the literature and identifies the molecular structures in VO-based lubricants which have been used to improve performance. The specific roles that size, type, number, position, spatial arrangement, and symmetry play in determining lubricating functionality were highlighted. Data were systematically collected to identify the contributions of major structural components and relate them to specific physical functionality measurables. The relationships were presented to reveal structure–function trends. Empirical predictive relationships between flow and thermal transition properties and structures were established. Molecular mass was revealed to be a fundamental determinant of viscosity and transition temperatures, but these properties were shown to also be influenced by other structural factors such as polar functional groups, branching, and symmetry. Almost all the examined viscosity data plotted versus molecular mass are enclosed within the 95% prediction band of an exponential rise to a maximum function (R2 = 0.7897). Generally, for both flow and thermal transition, a given structure versus function follows simple linear or exponential functions with unbranched VO-based lubricants, lending themselves more easily to strong correlations. This review is a first step towards comprehensively relating structure to lubrication function. The revealed relationships of structural contributions to the lubricating functionality of VO-based lubricants provide insights that may be used to extend the ranges of chemical and physical properties of some molecular architectures examined.

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A high-temperature-triggered crosslinking reaction to achieve excellent intrinsic flame retardancy of organic phase change composites

Liu,

Xiao,

Wang

et al. 2024

Mater. Horiz.

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Exploiting aromaticity in fatty terephthalate diesters to enhance melting point and prevent polymorphism

Cited by 4 publications

References 54 publications

Nanocellulose-based composite phase change materials for thermal energy storage: status and challenges

Nanocellulose-based composite phase change materials for thermal energy storage: status and challenges

Fundamental Structure–Function Relationships in Vegetable Oil-Based Lubricants: A Critical Review

A high-temperature-triggered crosslinking reaction to achieve excellent intrinsic flame retardancy of organic phase change composites

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