Cooperative atomic emission spectrum as a key probe of entanglement dynamics of an independent and a classically-pumped qubits pair is showed and investigated. The qubits are initially maximally-entangled while they penetrate a detuned, single-photon and coherent cavity embedded in nonlinear media. The system Hamiltonian; that is a nonlinear and a time-dependent system, is diagonalized and the time evolution unitary operator in an exact form is derived. Various characteristics are monitored while observations are theoretically documented—via tracing the field state tomography—and experimentally calibrated. Cooperation and decoherence as well as the statistics of the emitted radiation are discussed and analyzed in terms of the other phenomena. We show that, a measurement of the spectrum outputs represent a highly effective key calibration for entanglement attributes, where complete time dynamics may be predicted with a high considerable accuracy. The most striking feature realized is that, on high detuned interaction, a full matching of these phenomena outputs can be achieved regardless of the absence or presence or pumping. Once the pumping starts, a partial dephasing is encouraged, thus, the spectrum is inversely but slightly affected, nevertheless, matching remains highly closed. Within various surroundings of Kerr materials of different Kerr constants, that is an additional source of an effective dephasing, spectrum rapidly oscillates and so also entanglement that shows rapid Rabi oscillations during its fast degradation depending on the detuning width. However, on measuring the intracavity field state tomography, measurements confirm such a matching, that is, calibration is well documented.