This report presents an experimental study, through pressure distributions, of the homogeneous nucleation and condensation of initially superheated ammonia vapor during its expansion in a low Mach number supersonic nozzle. The results of the experiments are compared with the classical nucleation theory of Becker and Doring or Frenkel-Zeldovich, on the basis of the predicted pressure and temperature at which condensation would occur starting from a given stagnation condition.It is found that ammonia shows far less supersaturation than this theory predicts. The effect of arbitrary corrections to the surface tension shoved that a further reduction in surface tension of the drop relative to the flat.,film value gives better agreement between measured and predicted pressure distributions. Even better agreement is obtained without a surface tension correction if we assume that the nucleation rate is greater by a factor of 1017. This seems to lend some support to the recerst theories of Lothe and Pound (2 8 ) and Oriani and Sundquist(30)concerning gassification corrections to the free energy of formation of critical droplets. It is not certain however how much of this correction can be assigned to uncertainties in surface tension, and how much to the 'gassification' effect.