The main objective of this study is to evaluate the effect of the preparation
of the nanofluids based on the interactions between the surfactants,
nanoparticles, and brine for being applied in ultra-low interfacial
tension (IFT) for an enhanced oil recovery process. Three methodologies
for the addition of the salt–surfactant–nanoparticle
components for the formulation of an efficient injection fluid were
evaluated: order of addition (i) salts, nanoparticles, and surfactants,
(ii) salts, surfactants, and then nanoparticles, (iii) surfactants,
nanoparticles, and then salts. Also, the effects of the total dissolved
solids and the surfactant concentration were evaluated in the interfacial
tension for selecting the better formulation of the surfactant solution.
Three nanoparticles of different chemical natures were studied: silica
gel (SiO2), alumina (γ-Al2O3), and magnetic iron core–carbon shell nanoparticles. The
nanoparticles were characterized using dynamic light scattering, zeta-potential, N2 physisorption
at −196 °C, and Fourier transform infrared spectroscopy.
In addition, the interactions between the surfactant, different types
of nanoparticles, and brine were investigated through adsorption isotherms
for the three methodologies. The nanofluids based on the different
nanoparticles were evaluated through IFT measurements using the spinning
drop method. The adsorbed amount of surfactant mixture on nanoparticles
decreased in the order of alumina > silica gel > magnetic iron
core–carbon
shell nanoparticles. The minimum IFT achieved was 1 × 10–4 mN m–1 following the methodology
II at a core–shell nanoparticle dosage of 100 mg L–1.