Anhydrous
calcium chloride (CaCl2) can improve the problems
of long fracture time and low efficiency in fracturing hard rocks
with soundless cracking agents (SCAs), but the effect of the proportion
of CaCl2 on the expansion properties of SCAs and its optimal
ratio are less studied. In this paper, a comparative analysis of SCAs
with different contents (0, 0.4, 0.8, 1.2, and 1.6 wt %) of CaCl2 was performed. The macroscopic morphology, expansive pressure,
hydration temperature, and potential were monitored using a static
strain system and a temperature and voltage acquisition system, respectively,
to investigate the effect of CaCl2 on the performance of
the SCA. The results showed that CaCl2 could improve the
hydration efficiency of the SCA. Compared with group “a”
(0%), the volume expansion ratio of SCA in group “e”
(1.6%) decreased by 17.9%, the initiation time of expansive pressure
development and the time required for reaching the peak pressure were
reduced by 96.25 and 96.48%, respectively, the peak expansive pressure
was increased by 109.02%, and the time for reaching the peak temperature
was reduced by 92%. The catalytic and adsorption effects of CaCl2 promoted the hydration of calcium silicate hydrate (C–S–H),
which shortened the “dormant” period of SCA, increased
the peak expansive pressure, improved the lag of peak temperature
development, and significantly improved the hydration efficiency.
The maximum potential gradually decreased, the minimum potential first
decreased, increased, and then decreased, and the peak expansive pressure
decreased with the increasing of the maximum hydration potential.
The mechanism of the effect of CaCl2 on the hydration of
SCA was explained according to the development of potential and catalytic
principles. Considering safety and economy, the addition of 1.2% CaCl2 is preferred to enhance the hydration performance of SCA.
This study is important for SCA applications in industry.