As an eco-friendly working fluid, carbon dioxide or R744 is expected to
substitute for the existing working fluids used in heat pump systems. It is,
however, challenged by the much higher heat rejection pressure in
transcritical cycle compared with the traditional subcritical cycle using
freons. There exists a worldwide tendency to utilize blend refrigerants as
alternatives. Therefore, a new binary blend R744/R161 in this research is
proposed in order to decrease the heat rejection pressure. Meanwhile, on
mixing R744 with R161, the flammability and explosivity of R161 can be
suppressed because of the extinguishing effect of R744. A transcritical
thermodynamic model is developed, and then the system performances of heat
pump using R744/R161 blend are investigated and compared with those of pure
R744 system under the same operation conditions. The variations of heat
rejection pressure, heating coefficient of performance, unit volumetric
heating capacity, discharge temperature of compressor and the mass fraction
of R744/R161 are researched. The results show that R744/R161 mixture can
reduce the heat rejection pressure of transcritical heat pump system.