“…So far, many mechanisms for bismuthrelated NIR luminescence have been shown, which included different oxidation states of bismuth, the presence of Bi clusters and the presence of BiO or Bi 2 dimers [3], [7], [8], [9], [10]. Recently, most scienti c teams have considered that the cause of broadband luminescence is due to the existence of bismuth active centers (BACs), where multiple BACs can be mutually excited in different types of glasses [11], [12], [13], [14], [15]. Interestingly, the spectral properties can be tuned by changing the structural network of the glass, and consequently, by the glass composition.…”