Ti-Cr-and Ti-Mn-based alloys were prepared to be low-and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen storage properties were investigated. The alloy pair Ti 0.9 Zr 0.1 Mn 1.4 -Cr 0.35 V 0.2 Fe 0.05 /TiCr 1.55 Mn 0.2 Fe 0.2 was optimized based on the comprehensive performance of the studied alloys. The product hydrogen with a pressure of 100 MPa could be produced from 4 MPa feed gas when hot oil was used as a heat reservoir.