An experimental investigation of slug flow around 90 horizontal bend is presented. This paper demonstrates the visual observations during the onset of hydrodynamic slugs. It also presents the axial development of slug flow downstream a horizontal 90 bend. The available slug flow correlations are tested against the experimental results. Air-Silicone oil (viscosity 5 mPa.s) experiments were conducted in a horizontal test section of a 68 mm ID. The behaviour of slug characteristics was studied at 5D upstream and four locations (10D, 40D, 69D and 75D) downstream of the bend using ECT and WMS. The flow around the bend was observed using a high speed imaging system. This work demonstrates that at low gas flow rate hydrodynamic slug flow is mainly generated from the Kelvin-Helmholtz instability. While at high gas superficial velocities (>2.29m.s-1), slugs are developed from the coalescence of roll waves travelling at different velocities. Horizontal 90° bends have inconsiderable effects on the behaviour of slugs. This is due to that the phase separation and momentum transfer being insignificant. The horizontal bend has a minimum influence on the velocity and frequency of the flow structure.