Moderate and intense low-oxygen dilution oxy-coal combustion
(MILD-OCC)
technology is prospective as a result of its high thermal efficiency,
low NO
x
emission, and applications for
carbon capture and sequestration. MILD-OCC experiments were carried
out on the flat flame burner combustion facility where the diffusion
flamelet can provide the stable hot coflow of the fixed temperatures
and oxygen volume fractions. The flue gas species concentrations at
different axial heights above the burner tip were measured by the
flue gas analyzer. First, pulverized coal particle combustion experiments
under CO2, N2 and Ar dilution with different
coflow temperatures and oxygen volume fractions were carried out to
quantitatively separate thermal and fuel NO. The NO formation kinetics
were obtained through nth-order Arrhenius nonlinear
fitting to calculate the relative contributions of thermal and fuel
NO. Second, the comparison between the experiments of coal and char
combustion was made to quantitatively separate the formation and reduction
of volatile NO and char NO. Finally, different concentrations of initial
NO were added to the oxidizer to simulate recycled NO, and the experiments
on the influence of different concentrations of recycled NO were conducted
to quantitatively separate the recycled NO reburning. Therefore, the
NO formation and reduction mechanisms during the whole process of
MILD-OCC were quantitatively separated, and their relative contributions
were identified. With the increase of the coflow temperature from
1473 to 1873 K under the condition of 10% O2, the relative
contribution rate of volatile NO reduction to fuel NO decreases from
25 to 17%, with the relative contribution rate of char NO reduction
to fuel NO increasing from 2 to 9% and the relative contribution rate
of recycled NO reburning to fuel NO increasing from 7 to 19%. The
results can provide a comprehensive and quantitative perspective on
the NO
x
routes and the control method
of low NO
x
emissions for MILD-OCC.