One of the methods commonly used to treat biomass waste, including rice husks, is pyrolysis and gasification, both of which produce smoke that can disturb the surrounding environment. This study aims to optimize the conversion process of smoke released in the pyrolysis process of rice husks into two products at once, namely liquid smoke and producer gas. This study designed a Liquid Collection System (LCS) with a shell and tube type knock-down condenser mechanism where the hot smoke is cooled so that the components of the condensed smoke (become liquid smoke) are separated from the non-condensable components (become producer gas). The composition of the LCS coolant, a mixture of Ethylene Glycol and Water, is simulated with the help of Computational Fluid Dynamics (CFD) software to optimize the heat transfer effectiveness value obtained. The simulation results show that the heat transfer efficiency of the volume variation of Ethylene Glycol in the mixture with the volume ratio of Ethylene Glycol and Water is 0:100, 10:90, 20:80, and 30:70 is 9.43%, 13.21%, 15.32%, and 15.43%, respectively. The highest efficiency value was obtained at the highest Ethylene Glycol content, which was a ratio of 30:70.