The effect of adsorption on momentum a u and thermal a T accommodation coefficients and effective thermal conductivity ͗k f ͘ of Ar vapor-filled Pt nanogap and nanocavity is examined using nonequilibrium molecular dynamics ͑MD͒ simulations. For the accommodation coefficients, the increase in solid-fluid or fluid-fluid interatomic interactions within adsorbed layer causes transitions in magnitudes of a u and a T near Ar triple-point temperature. In the nanogap, ͗k f ͘ MD results are in close agreement with the available closed-form solution for transition-flow regime, i.e., Knudsen number 0.1Ͻ Kn L Ͻ 10, using the MD results of a T. In the nanocavity, the adiabatic sidewalls do not significantly alter the gas mean free path and ͗k f ͘, and the sparse adsorption coverage on the sidewalls results in a negligibly small fluid circulation by surface diffusion under a temperature gradient.