The demulsification and dewatering of the W/O emulsion are widely used in petrochemical industry, oilfield exploitation, and resource and environmental engineering. However, efficiently treating emulsion via traditional single methods. In this study, a new double-field coupling demulsification and dewatering device is proposed, where the conical structure of the device is double spherical tangential type. The numerical model for double-field coupling is established, especially, the population balance model (PBM) is used to simulate the coalescence and breakup of dispersed droplets under the double-field coupling action. And the effects of three conical structures on the internal flow and separation efficiency are analyzed. Results show that the conical structure has a significant effect on the coalescence of droplets, especially the double spherical tangential cone is more conducive for improving the coalescence ability of small droplets and improving the separation efficiency of the device. After optimization, the optimal R value of the double spherical tangential coupling device is 300 mm, and the separation efficiency can be up to 96.32%, which is 6.13% higher than the separation efficiency of the straight double-cone coupling device.