We present Doppler resolution limited spectra of the P(I) and R(J) multipfets for .I $ IO of the IO-pm CO stretch band of 12CD3's0H using a tunable diode laser. Relative frequencies within the multiplets accurate to t0.0002-0.0005 cm-' are obtained, but no absolute frequencies are given. We are able to assign most of the hindered rotation and K substructure in these multiplets. The assignments are based on analyses of Stark-ditference spectra combined with the ground-state microwave data and the intensity variations which are expected theoretically. The ground and excited state A, K = 1 asymmetry splitting parameters are measured to be S; = (8.5450 2 0.0080) x lo-$ cm-' and S; = (9.7706 zt 0.0080) x 10e3 cm-', respectively. The ground-state value agrees well with the microwave results. A rapid-scan system for recording data and a computer-aided technique for calibrating and plotting the spectra are described.