To develop a new composite adsorbent with high performance, fir sawdust and CaCl 2 are selected as raw materials. The mass transfer is enhanced by carbonizing and activating the sawdust and heat transfer is enhanced by adding expanded graphite into the adsorbent. The effect of the preparation temperature and the expanded graphite content on the adsorption performance is investigated. The results show that the new adsorbent exhibits a high adsorption performance due to its high porosity, uniform distribution and high content of CaCl 2 and high thermal conductivity. Also, the experimental results indicate that the rate of ammonia adsorption on the adsorbent depends on the expanded graphite content and the carbonization and activation temperature. The adsorbent prepared at 500°C and with the expanded graphite content of 30% has the best performance in terms of the adsorption refrigeration, which adsorbs ammonia as high as 0.37 g g 1 at 10 min. Adsorption refrigeration systems powered by low grade thermal energy such as waste heat or solar energy have drawn considerable attention due to the benefits of simple control, silent operation with no vibrations and lower operation costs [1,2]. However, the widespread acceptance of the adsorption systems is hindered by its relatively poor performances and large size due to limited properties of adsorbents [3]. The adsorption capacity of physical adsorbents can hardly exceed 30wt% [4]. The adsorption capacity of chemical adsorbents (calcium chloride, strontium chloride, barium chloride, etc.) is rather high, however, the problem of swelling and agglomeration always occurs during the adsorption and desorption process, which results in a poor heat and mass transfer and prevents putting the single chemical adsorbents into practice [5]. In order to overcome these disadvantages, several works have been carried out [6][7][8][9][10]. Aristov and his coworkers, Wang and Zhang developed a new composite adsorbent by confining chemical adsorbents (CaCl 2 , BaCl 2 , MgCl 2 , etc.) into the open pores of a porous host matrix (silica gel, alumina, active carbon, etc.) [11][12][13][14][15]. All their studies showed that the composite adsorbent has a higher adsorption capacity and can solve the problem of swelling and agglomeration of chemical adsorbents [16][17][18][19]. However, the content of chemical adsorbents in the composite adsorbent prepared by impregnating a porous host matrix with chemical adsorbents is only 30%-40%, leading to a great reduction of the cycle uptake per unit mass of composite adsorbent. In addition, to improve the thermal conductivity, the consolidation of adsorbents is often needed, which weakens the mass transfer due to some channels of the adsorbents being blocked. That is to say, there is a contrast between enhanced mass transfer and enhanced heat transfer.To overcome the shortage of low content of chemical adsorbents in the composite adsorbents and solve the contrast between enhanced mass transfer and enhanced heat transfer, a new method for the preparation o...