2017
DOI: 10.1155/2017/2703986
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Experimental Investigation of Isothermal Section of the B-Cr-Fe Phase Diagram at 1353 K

Abstract: The isothermal section of the B-Cr-Fe ternary system was studied experimentally at 1353 K. X-ray diffraction and scanning electron microscopy equipped with EDX analyzer were used for determination of phase equilibria and composition of the coexisting phases in the B-Cr-Fe model alloys after long-term annealing (1500–2205 h). Two iron borides FeB and Fe2B, six chromium borides Cr2B, Cr5B3, CrB, Cr3B4, CrB2, and CrB4 and also iron and chromium solid solutions (α(Fe,Cr), α(Cr,Fe), γ(Fe,Cr)) and β-rhombohedral B w… Show more

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Cited by 9 publications
(12 citation statements)
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“…The highest intensity and increased number of peaks of the obtained phases occur in the angular range of 35 • to 55 • . The resulting phases correspond to the phases that can be read from the Fe-Cr-B, Fe-CB, and Cr-BC phase equilibrium diagrams and correspond to the results of other researchers who take up this problem [43][44][45].…”
Section: Resultssupporting
confidence: 69%
“…The highest intensity and increased number of peaks of the obtained phases occur in the angular range of 35 • to 55 • . The resulting phases correspond to the phases that can be read from the Fe-Cr-B, Fe-CB, and Cr-BC phase equilibrium diagrams and correspond to the results of other researchers who take up this problem [43][44][45].…”
Section: Resultssupporting
confidence: 69%
“…The phases that can be attributed to this content are Fe 3 (C,B) or Fe 23 (C,B) 6 . As a result of the application of the Cr-B mixture in the remelting zone, a chemical composition was obtained corresponding to the complex phase (Cr,Fe) 2 B, (Fe,Cr) 3 (C,B) [ 38 , 39 , 40 , 41 , 42 , 43 , 44 ]. In the photos of microstructures 6a and 6d, white precipitates are visible.…”
Section: Resultsmentioning
confidence: 99%
“…The Fe-B-X alloys were prepared from high-purity powders (Fe-99.98 % or 99.96 %, B-99.95 %, C-99.90 %, Cr-99.99%, Mn-99.98 % or 99.95 %, V-99.80 %, W-99.90 %). Details on the production process can be found in published studies on phase equilibria and/or thermodynamic modelling studies [ 38 , 39 , 40 , 41 , 42 , 43 , 44 , 45 , 46 ]. The mixed powders were pressed into cylindric compacts using a uniaxial pressing machine.…”
Section: Methodsmentioning
confidence: 99%
“…The investigative Fe-B alloys of the following type: B-Fe-C, B-Fe-Cr, B-Fe-Mn, B-Fe-V, and B-Fe-W, were chosen as such, so as to be able to isolate as much as possible the effect of the third compositional element present in the iron borides on their nanomechanical properties. In general, the solubility of tungsten (W) and carbon (C) in iron borides is low, while the solubility of chromium (Cr) reaches up to 15 at.% for Fe 2 B phase, and 16 at.% for FeB boride at 1353 K [ 38 ]. Manganese (Mn) can completely replace iron in these borides [ 39 ], therefore it is interesting to study the influence of these elements on borides mechanical properties.…”
Section: Introductionmentioning
confidence: 99%