A new pulsed coaxial plasma generator (PCPG) has been developed in order to allow for investigating particle generation in the quench of a propagating jet. The related process provides an extremely transient environment which is characterised by initially high energy and charge densities, steep temperature gradients and short particle residence times. The combination of high quench rates and high charge densities, which can not be obtained in conventional reactors such as in flames or quasi stationary plasmas, provide in fact a potential for "freezing" of non-equilibrium phases and for tailoring particle characteristics by means of controlling particle-particle interactions. The pulsed plasma is characterised by means of determining the energy coupling, the charge density, the expansion behaviour, and the evolution of temperature. Particle properties such as primary particle size and aggregate structure are determined for varying process parameters, namely energy coupling, precursor injection, and ambient pressure.