Nuclear magnetic resonance, as an extensively recognized
technique,
is utilized to measure the pore size distribution of shales. However,
the pore size distribution interpreted by nuclear magnetic resonance
noticeably relies on the surface relaxivity (SR) of shales, which
is influenced by many factors, including the measurement approach
and mineralogical compositions. This paper chiefly deals with two
approaches to measuring the surface relaxivity of shales based on
a one-dimensional relaxation model. In continuing, the effects of
mineralogical compositions and measurement approaches on the surface
relaxivity of shales are methodically assessed. The surface relaxivity
of shales is measured to be 1.34–2.59 μm/s by the spin
echo approach and 1.40–2.44 μm/s based on the Carr–Purcell–Meiboom–Gill
approach. Compared with the nitrogen adsorption approach, the suggested
methods are more suitable for measuring the SR of shales. The achieved
results reveal that the shale SR is negatively correlated with quartz
and calcite and is positively correlated with pyrite and clay. In
particular, the clay content seems to be the most vital mineral factor
in determining the SR of shales.