A study was made to verify the influence of the gas mixture flow on the iron sintering process with simultaneous surface enrichment of alloying elements by hollow cathode discharge. In this process, two independent cathodes formed an annular discharge: (1) a pressed cylindrical sample of iron powder, acting as the central cathode, was placed concentrically inside an external (hollow) cathode; (2) the external cathode, machined from a AISI 310 steel bar, acted both to confine the geometry of the plasma and as a source of alloying elements (Cr and Ni). The sintering was carried out at 1423 K, for a period of 7.2 × 103 s, under a gas mixture of 80% Ar + 20% H2 and a pressure of 399 Pa, at flow rates of 2 × 10−6, 5 × 10−6, and 8 × 10−6 m3 s−1, with an inter-cathode radial space of 5.8 mm. The discharge was generated using a pulsed voltage power source with a 200 µs period. The gas mixture flow plays an important role both in the cleanliness of the sintering atmosphere (reflected in the electric power utilized to maintain the sample's temperature) and in the amount of metallic atoms deposited on the sample's surface (as a result of the sputtering and the oxidation/reduction process on the cathode surfaces).