SUMMARYThis study investigates the effect of a heat-treatment upon the thermo-mechanical behaviour of a model cement-based material, i.e. a normalized mortar, with a (w/c) ratio of 0.5. First, a whole set of varied experimental results is provided, in order to either identify or validate a thermo-mechanical constitutive model, presented in the second paper part. Experimental responses of both hydraulic and mechanical behaviour are given after different heating/cooling cycling levels (105, 200, 300, 400 • C). The reference state, used for comparison purposes, is taken after mass stabilization at 60 • C. Typical uniaxial compression tests are provided, and original triaxial deviatoric compressive test responses are also given. Hydraulic behaviour is identified simultaneously to triaxial deviatoric compressive loading through gas permeability K gas assessment. K gas is well correlated with volumetric strain evolution: gas permeability increases hugely when v testifies of a dilatant material behaviour, instead of contractile from the test start. Finally, the thermo-mechanical model, based on a thermodynamics approach, is identified using the experimental results on uniaxial and triaxial deviatoric compression. It is also positively validated at residual state for triaxial deviatoric compression, but also by using a different stress path in lateral extension, which is at the origin of noticeable plasticity.