Dental phosphate-bonded investments have been widely used to cast the prostheses of alloys with high melting temperatures like cobalt-chromium alloy and titanium. 1 3) These investments are typically composed of refractory (80 90%) powders and binder materials. 4) Silica (SiO2) is the most popular refractory material, while Al2O3, MgO, ZrO2 and other oxides are occasionally utilized, particularly in the casting of titanium. Both ammonium dihydrogen phosphate and magnesium oxide (MgO) are commonly used as binder materials. When mixing powder with water, the chemical reaction for the binder system that causes an investment to set is generally written as follows 5,6) :With the recent development of quick-heat type dental investments, particle size has become finer, averaging less than 10 μm. As a consequence, the fi ne powder can drift into the atmosphere during unpacking, measuring or mixing and can be easily inhaled. It is known that inhaled silica powder can induce lung or respiratory diseases, 7,8) potentially leading to cancer. 9) Thus, fi ne powders are a Abstract: Although silica is the most popular refractory material, it is known that inhaled silica powder can induce lung or respiratory diseases, potentially leading to cancer. The purpose of this study was to develop experimental paste-type phosphate-bonded investments fabricated with colloidal silica solutions. Paste 1 was prepared by mixing cristobalite powder of 80 g with 30 cc monomagnesium phosphate solution. To investigate the effects of colloidal silica solution within paste 2, three volumes (A: 20 cc, B: 25 cc, C: 30 cc) were prepared with 15 g of MgO each. Basic properties and fi t of the casting were compared to commercial phosphate-bonded investment and evaluated. The setting times for A, B and C were statistically different. The quickest setting time was measured from U. The fi red strength of U was remarkably greater than those of others. The setting expansion of U was obviously greater than those of the experimental investments. The average value of A was statistically higher than that for B. C expanded minimally while setting. The expansion percentages at 850ºC were no signifi cant differences among experimental investments. In addition, that of U during the entire heating was remarkably low. The degree of the fi t differed signifi cantly between U and A because setting expansion of A was insuffi cient. Although the results are not optimal, the newly developed paste-paste type phosphate-bonded investments produced in this study still offer potential as alternative investment systems due to their excellent fl uidity, manipulation and reasonable basic properties.