2012
DOI: 10.1103/physrevb.85.224202
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Experimental and theoretical study of Ti-6Al-4V to 220 GPa

Abstract: We report results from an experimental and theoretical study of the ternary alloy Ti-6Al-4V to 221 GPa. We observe a phase transition to the hexagonal ω-phase at approximately 30 GPa, and then a further transition to the cubic β-phase starting at 94-99 GPa. We do not observe the orthorhombic γ and δ phases reported previously in pure Ti. Computational studies show that this sequence is possible only if there is significant local atomic ordering during the compression process, yet insufficient atomic diffusion … Show more

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Cited by 15 publications
(26 citation statements)
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“…Therefore, we infer that the dynamic α→β transformation might occur during the α + β forging of the large-scale Ti-5553 alloy billet. In addition, the high pressure and the related stress concentration of the α + β forging may also lead to the α→ω→β transformation in the sub-transus forging [ 21 , 22 ].…”
Section: Discussionmentioning
confidence: 99%
“…Therefore, we infer that the dynamic α→β transformation might occur during the α + β forging of the large-scale Ti-5553 alloy billet. In addition, the high pressure and the related stress concentration of the α + β forging may also lead to the α→ω→β transformation in the sub-transus forging [ 21 , 22 ].…”
Section: Discussionmentioning
confidence: 99%
“…For bcc, the symmetry constraints and fit to elastic constants mean that agreement with experiment is exact for the slope at the Γ point, so the general similarity with neutron data is unsurprising and trends across the group can be readily seen. It is notable that Li and Na, which are unstable with respect to fcc at low temperature, have stable bcc phonon spectra, unlike other elements such as Ti and Zr, which are calculated to have negative bcc shear moduli at 0K 13,25,26 , and transform to bcc at high temperatures due to soft T1N modes. Figures 5 and 6 show phonon spectra for Li and Cs, other elements being similar (Supplemental Figure 3).…”
Section: Phononsmentioning
confidence: 99%
“…In general, Ti and Ti alloys are quite attractive for aerospace, medical, and industrial applications [1][2][3][4], of which gamma-titanium aluminide (γ-TiAl) has been considered as one of the topmost candidates for high-temperature structural material due to its low density and high specific modulus and strength [5][6][7][8][9]. However, the intricate processing behavior, particularly the poor ductility and the low hot workability appears to be the main obstacle for a wide industrial application of γ-TiAl alloys [9].…”
Section: Introductionmentioning
confidence: 99%