Experimental and theoretical studies on bis(chlorocarbonyl)trisulfane, ClC(O)SSSC(O)Cl

Tobon, Y.; Cozzarín, Melina V.; Védova, Carlos O. Della; Romano, Rosana M.

doi:10.1016/j.molstruc.2009.04.025

Cited by 2 publications

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References 25 publications

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“…Here, we present a complete vibrational study of ClC(O)SSCl, including the IR and Raman spectra of the net liquid and the IR spectrum of the compound isolated in solid Ar and N 2 matrixes. The bands observed in the experimental spectra have been assigned on the basis of comparisons (i) with the calculated IR and Raman spectrum and (ii) with the spectra of related molecules, particularly ClC(O)SCl, 3,4 ClC(O)SSC(O)Cl, 18 ClC(O)SSSC-(O)Cl, 19 ClC(O)SSCH 3 , 20 and ClC(O)SSCF 3 . 20 The IR and Raman spectra of liquid ClC(O)SSCl are shown in Figure 6.…”

Section: ' Introductionmentioning

confidence: 99%

Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl

et al. 2011

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ClC(O)SSCl was prepared by an improved method by the reaction of [(CH(3))(2)CHOC(S)](2)S with SO(2)Cl(2) in hexane. The photoelectron spectra in the gas phase present four distinct regions, corresponding to ionizations from electrons formally located at the S, O, and Cl atoms and at the C═O bond. The vibrational IR and Raman spectra of the liquid were interpreted in terms of the most stable syn-gauche conformer (the O═C double bond syn with respect to the S-S single bond and the C-S single bond gauche with respect to the S-Cl single bond) in equilibrium with the less stable anti-gauche form, both occurring in two enantiomeric forms. The randomization process between the conformers was induced by broad-band UV-visible irradiation in matrix conditions, and several photoproducts were identified by FTIR spectroscopy. The experimental results were complemented by theoretical calculations.

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Section: ' Introductionmentioning

confidence: 99%

Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl

et al. 2011

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Light induced reactions in cryogenic matrices

Fausto

Gómez‐Zavaglia

2010

Photochemistry

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This chapter centers on light-induced reactions in cryogenic matrices, ranging from conformational isomerizations to complex bond-breaking/bond-forming processes. Recent progress in the photochemistry involving direct participation of the matrix noble gas atoms as reactants to form covalently bound noble gas containing molecules will also be discussed. Finally, infrared-induced reactions in cryomatrices will be considered.

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Experimental and theoretical studies on bis(chlorocarbonyl)trisulfane, ClC(O)SSSC(O)Cl

Cited by 2 publications

References 25 publications

Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl

Vibrational and Valence Photoelectron Spectroscopies, Matrix Photochemistry, and Conformational Studies of ClC(O)SSCl

Light induced reactions in cryogenic matrices

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