Experimental and theoretical investigation of mild steel corrosion control in acidic solution by Ranunculus arvensis and Glycine max extracts as novel green inhibitors
“…The optimum concentration of GWH extract was 400 ppm, while a higher or lower concentration could cause a reduction in the retardation coefficient. The same behavior was also found in other studies [ 17 , 25 ]. The range of E corr values for specimens with the green inhibitor was −532 to −507 mV.…”
Section: Resultssupporting
confidence: 90%
“…Their outcomes showed that the corrosion resistance increased to 88 % when the extract concentration was about 400 ppm. Sajadi et al [ 17 ] studied the properties of Ranunculus arvensis and Glycine max extracts for mild steel in 1 M HCl solution. They demonstrated that adsorption mechanism for both inhibitors followed by the Langmuir model through physical adsorption.…”
“…The optimum concentration of GWH extract was 400 ppm, while a higher or lower concentration could cause a reduction in the retardation coefficient. The same behavior was also found in other studies [ 17 , 25 ]. The range of E corr values for specimens with the green inhibitor was −532 to −507 mV.…”
Section: Resultssupporting
confidence: 90%
“…Their outcomes showed that the corrosion resistance increased to 88 % when the extract concentration was about 400 ppm. Sajadi et al [ 17 ] studied the properties of Ranunculus arvensis and Glycine max extracts for mild steel in 1 M HCl solution. They demonstrated that adsorption mechanism for both inhibitors followed by the Langmuir model through physical adsorption.…”
“…Leaves, stems, barks, flowers, seeds, and their derivatives have all been successfully used for the biosynthesis of nanoparticles 40 , 41 . The previous article reported the active agents found in RA extract 42 , which allow stabilization and reduction of Ag + ions in this study.…”
Asymmetric Configuration (As-Co) in the electrochemical noise (EN) was used to evaluate Ranunculus Arvensis / silver nanoparticles (RA/Ag NPs) as corrosion inhibitor for aluminum alloy (AA 2030) when gets exposed to 3.5% NaCl media. The ECN results of Asymmetric Configuration (As-Co) and Symmetric Configuration (Sy-Co) were interpreted using wavelet and statistical methods. The standard deviation of partial signal (SDPS) plots derived using of wavelet. The SDPS plot of As-Co demonstrated that the quantity of electric charge (Q) decreased with the addition of the inhibitor up to the optimum amount (200 ppm) due to the decreased corrosion rate. Moreover, the use of As- Co leads to record signal of one electrode and prevent recording extra signals arising from two identical electrodes which confirmed by the statistical parameters. The As-Co made of Al alloys were more satisfactory for estimating inhibiting effect of RA/Ag NPs compared to Sy-Co. Besides, aqueous extract of Ranunculus Arvensis (RA) plant as reducing agent mediates the synthesis of silver nanoparticles (RA/Ag NPs). The prepared NPs have been elaborately characterized using Field-Emission Scanning Electron Microscopy (FESEM), X-Ray Diffraction (XRD) analysis, and Fourier-Transform Infrared Spectroscopy (FT-IR) that revealed suitable synthesize of the RA/Ag NPs.
“…2 ; a) methyl nicotinate (C 7 H 7 NO 2 ), and b) pyridine-4-carbohydrazide (C 12 H 10 N 4 O 5 S). Methyl nicotinate and pyridine-4-carbohydrazide of the castor oil leaf contain heteroatoms of O, N and S. Presence of the heteroatoms, antioxidants as well as lengthy hydrocarbon chain revealed that the material is highly suitable for corrosion control [ 6 , 16 , 18 , 21 , 24 ]. Fig.…”
Section: Resultsmentioning
confidence: 99%
“…It undergoes chemical and/or electrochemical reaction with its environment to attain stability. In general, chemical reactivity of metal is connected to its natural propensity of oxidation, as it has tendency to return to its natural state by chemical reactions with the constituents of the environment [ 5 , 6 ]. Such oxidative or chemical destruction of metal is regarded as corrosion.…”
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