Experimental Analysis on the Molten-Phase Dewetting Characteristics of AuPd Alloy Films on Topographically-Structured Substrates

Abstract

AuPd nanoparticles are formed on fluorine-doped tin oxide (FTO) by a nanosecond laser irradiation-induced dewetting process of deposited AuPd films. In particular, we analyze the effect of the surface topography of the substrate on the dewetting process and, so, on the final mean size of the formed nanoparticles. In fact, we used two supporting FTO substrates differing in the surface topography: we used a FTO layer which is un-intentionally patterned since it is formed by FTO pyramids randomly distributed on the glass slide as result of the deposition process of the same FTO layer, namely substrate A. We used, also, a further FTO substrate, namely substrate B, presenting, as a result of a chemical etching process, a higher roughness and higher mean distance between nearest-neighbor pyramids with respect to substrate A. The results concerning the size of the obtained AuPd NPs by the laser irradiations with the laser fluence fixed shows that the substrate topography impacts on the dewetting process. In particular, we found that below a critical thickness of the deposited AuPd film, the NPs formed on substrates A and B have similar size and a similar trend for the evolution of their size versus the film thickness (i.e., the dewetting process is not influenced by the substrate topography since the film does not interact with the substrate topography). On the other hand, however, above a critical thickness of the deposited AuPd film, the AuPd NPs show a higher mean size (versus the film thickness) on substrate B than on substrate A, indicating that the AuPd film interacts with the substrate topography during the dewetting process. These results are quantified and discussed by the description of the substrate topography effect on the excess of chemical potential driving the dewetting process.

Evolution of Ternary AuAgPd Nanoparticles by the Control of Temperature, Thickness, and Tri-Layer

“…The sublimation loss of Ag in this case was much lower compared to the pure Ag nanoparticles due to the inter-mixing with Au and Pd [29]. Furthermore, the atomic homogeneity of metal elements can improve with increased temperature, exceeding the melting point, as observed in previous results [36]; however, Ag can be extensively sublimated. with respect to the annealing temperature.…”

Characteristics of Pd and Pt Nanoparticles Produced by Nanosecond Laser Irradiations of Thin Films Deposited on Topographically-Structured Transparent Conductive Oxides

“…From a general point of view, this work completes our previous studies on the molten phase dewetting of pure (Au) or alloy (AuPd) metals films on transparent conductive oxides [17,40,41], extending these studies to other metals such as Pd and Pt whose nanostructuration by laser pulsed-induced dewetting is rarely studied (Pt) [42,43] or, practically, absent (Pd).…”

Nanostructuration of Thin Metal Films by Pulsed Laser Irradiations: A Review

“…Figure 64 summarizes some outlooks for the pulsed-laser use in nanostructuration. In this sense, the use of interfering lasers [31,61] of the pulsed-laser processing of metal films in liquids exploiting the Rayleigh-Taylor phenomenon [144,145] and the pulsed-laser processing of multielement (as alloyed) films or multilayered metallic films [146,147,148,149] will be the key approaches. In particular, in this last case, alloyed and multi-elemental nanostructures can be produced with innovative properties arising from the synergistic combination of the properties of the metallic components.…”